2010
DOI: 10.1107/s1600536810049640
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Bis(μ-2-phenylquinoline-4-carboxylato)-κ3O,O′:O3O:O,O′-bis[(2,2′-bipyridine-κ2N,N′)(2-phenylquinoline-4-carboxylato-κ2O,O′)cadmium(II)]

Abstract: The neutral binuclear title complex, [Cd2(C16H10NO2)4(C10H8N2)2], is centrosymmetric, with the inversion center generating the central (μ-O)2Cd2 bridge. The CdII ion is in a strongly distorted CdN2O5 penta­gonal-bipyramidal geometry, defined by two N atoms from one 2,2′-bipyridine ligand and five O atoms from three 2-phenyl­quinoline-4-carboxyl­ate ligands, one monodentate, two bidentate. Weak inter­molecular π–π inter­actions [centroid–centroid distance = 3.712 (3) Å] help to establish the packing of the stru… Show more

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