Bis(μ-N-benzyl-N-methyldithiocarbamato)-1:2κ³S,S′:S′;1:2κ³S:S,S′-bis[bis(N-benzyl-N-methyldithiocarbamato-κ²S,S′)thallium(III)]

Abstract

The molecule of the dinuclear title compound, [Tl2(C9H10NS2)6], possesses a crystallographically imposed centre of symmetry. Each TlIII atom is seven-coordinated by S atoms of four different dithio­carbamate anions in a distorted penta­gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C—H⋯S hydrogen-bond inter­action linking complex mol­ecules into chains running parallel to the b axis. Intramolecular C—H⋯S hydrogen bonds are also present.