“…As follows from the results of a number of studies on the formation of nanomaterials, in many cases their functional properties are determined by the chemical and thermal prehistory of the initial compositions and the mechanism of their formation [176,177,182,186,189,190,194,198,199,228,352,353]. It is also shown that solid-phase reactions are, in a certain sense, liquid-phase, since reactions in a solid system are activated with the transition of two-dimensional non-atomic phases (intergrain formations) to a liquid-like state, when the reaction rate increases sharply [216][217][218][219][220][221].…”