Although SrNbO2N with a bandgap of ≈1.9 eV has been considered as a promising photocatalyst for solar water splitting, its photocatalytic activity is generally very poor under ordinary conditions, primarily due to bad photocarrier generation, separation, and transportation. Herein, vertical SrNbO2N nanorod arrays are first achieved using a facile hydrothermal method with a nitridation process for solar‐driven photoelectrochemical (PEC) water splitting. The obtained SrNbO2N nanorod arrays exhibit vertical aligned nanorod morphology and high crystallinity, which are beneficial for photocarrier generation and charge carrier transportation. After being uniformly covered with CoOx nanoparticles, the SrNbO2N nanorod arrays present a photocurrent of 1.3 mA cm−2 at 1.23 VRHE, which is ≈2.6 times higher than that of a SrNbO2N nanoparticle thin film electrode, under irradiation by AM1.5G simulated sunlight. This PEC water splitting activity is one of the best values among all reported SrNbO2N electrodes. Thus, this work offers a new strategy to develop bimetal oxynitride nanorod arrays for PEC applications.