Blue light-emitting Quinoline armed Thiacalix [4]arene 3D-scaffold: A systematic platform to construct fluorescent liquid crystals with bio-imaging applications

Rathod, Suryajit L.; Sharma, Vinay S.; Sharma, Anuj S.; Athar, Mohd; Shrivastav, Pranav S.; Parekh, Hitesh M.

doi:10.1016/j.molstruc.2022.133830

Cited by 11 publications

(6 citation statements)

References 59 publications

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“…Generally, the rigidity of polymeric chains and the presence of amide bonds can significantly influence the T g values of thermosets. [25] The glass transition temperatures (T g ) value for G″ curve occurred at 176 °C (see Figure S4, Supporting Information).…”

Section: Thermal Propertiesmentioning

confidence: 99%

Reaction‐Induced Liquid Crystalline Polybenzoxazine Bearing Aromatic Amide Side Branches

Rafique,

Liu,

Said

et al. 2023

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In this study, a nematic phase structure is incorporated into polybenzoxazine to increase its thermal conductivity. A simple route for the synthesis of a thermally conductive polybenzoxazine containing liquid crystalline (LC) structure by grafting oligomeric p‐sulfophenylene‐terephthalamide (PSTA) is offered. Benzoxazine monomer of pHBA‐da is synthesized via Mannich reaction of p‐hydroxy benzoic acid, p‐formaldehyde, and dodecyl amine. After ring‐opening polymerization, the oligomer benzoxazine of OBZ─COOH is obtained. The OBZ─COOH/PSTA mixture is prepared by mixing PSTA with OBZ─COOH. Afterward, the grafted copolymer is named OBZ─PSTA copolymer. The liquid crystalline behavior of OBZ─COOH/PSTA is studied by polarized optical microscopy and small angle X‐ray scattering analysis. The results show that the OBZ─PSTA forms the LC structure during isothermal and non‐isothermal curing. The LC structure displays a floral textured nematic phase. The phase formation is induced by an amidation reaction. Due to the grafts of LC PSTA, the thermal conductivity of OBZ─PSTA is 0.296 W m−1 K−1, which is 26% greater than OBZ─COOH. The glass transition temperature (Tg) of OBZ─PSTA is 241 °C. The 5% (Td5) and 10% weight loss temperatures (Td10) of OBZ─PSTA are 346 and 362 °C, respectively.

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Section: Thermal Propertiesmentioning

confidence: 99%

Reaction‐Induced Liquid Crystalline Polybenzoxazine Bearing Aromatic Amide Side Branches

Rafique,

Liu,

Said

et al. 2023

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“…Rathod et al reported a cone-shaped thiacalix [4]arene appended with quinoline moieties that were stabilizing liquid crystallinity (Scheme 14). 62 The thiacalixarene core bearing bisubstituted quinoline units stabilized the Col h phase, when the other two hydroxyl groups were free (26c and 26d) and where the terminal chains were n-octyloxy and n-decyloxy units. In the case of tetrasubstituted thiacalix [4]arene derivatives, lower chain homologues exhibited Col h phases while the higher chain substituted compounds showed nematic phases (Figure 25).…”

Section: Calixarene Derivatives With Schiff Base Moeitiesmentioning

confidence: 99%

“…Distribution of parent calixarene linked quinoline derivative ( 27d ) in nematodes ( Caenorhabditis elegans ) (5 μM). (a) Nematode exposed with aqueous THF solution in the blue filter; (b) nematode exposed with aqueous THF solution in green filter; (c, d) nematode exposed with compound 27d in THF solvent . Reproduced with permission from ref .…”

Section: Calixarene Based Liquid Crystalsmentioning

confidence: 99%

“…In continuation with their work on triphenylene−calix [4]arene LCs, Yang and co-workers reported calixarene linked symmetrical triphenylene dimers (61,62) in good yields and investigated their mesomorphic properties. 91 The nature of the Scheme 31.…”

Section: Calix[4]arene Derivatives Containingmentioning

confidence: 99%

“…(a) Nematode exposed with aqueous THF solution in the blue filter; (b) nematode exposed with aqueous THF solution in green filter; (c, d) nematode exposed with compound 27d in THF solvent. 62 Reproduced with permission from ref ( 62 ). Copyright 2022 Elsevier.…”

Section: Calixarene Based Liquid Crystalsmentioning

confidence: 99%

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Calixarene Functionalized Supramolecular Liquid Crystals and Their Diverse Applications

et al. 2022

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Liquid crystals are considered to be the fourth state of matter with an intermediate order and fluidity in comparison to solids and liquids. Calixarenes are among one of the most versatile families of building blocks for supramolecular chemistry due to their unique vaselike structure that can be chemically engineered to have different shapes and sizes. During the last few decades, calixarenes have drawn much attention in the field of supramolecular chemistry due to their diverse applications in the fields of ion and molecular recognition, ionselective electrodes for catalysis, drug delivery, gelation, organic electronics and sensors, etc. Imbuing liquid crystallinity to the calixarene framework leads to functionalized calixarene derivatives with fluidity and order. Columnar self-assembly of such derivatives in particular enhance the charge migration along the column due to the 1D stacking due to the enhanced π−π overlap. Considering limited reports and reviews on this new class of calixarene based liquid crystals, a comprehensive account of the synthesis of calixarene liquid crystals along with their mesomorphic behavior and potential applications are presented in this review.

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Thiacalix[4]arene-based metal-organic framework/reduced graphene oxide composite for electrochemical detection of chlorogenic acid

Zhao

Niu

Pei

et al. 2023

Analytica Chimica Acta

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Blue light-emitting Quinoline armed Thiacalix [4]arene 3D-scaffold: A systematic platform to construct fluorescent liquid crystals with bio-imaging applications

Cited by 11 publications

References 59 publications

Reaction‐Induced Liquid Crystalline Polybenzoxazine Bearing Aromatic Amide Side Branches

Reaction‐Induced Liquid Crystalline Polybenzoxazine Bearing Aromatic Amide Side Branches

Calixarene Functionalized Supramolecular Liquid Crystals and Their Diverse Applications

Thiacalix[4]arene-based metal-organic framework/reduced graphene oxide composite for electrochemical detection of chlorogenic acid

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