1975
DOI: 10.1016/0022-2860(75)87014-1
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Bond-polarity: an order-disorder phenomenon?

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“…Likewise, Bent has generated a list of interesting parallels between the Kimball model for covalent species and packing models for ionic solids. , Not included in this list, however, is how the ionic model deals with so-called defect structures, though pursuit of this particular analogy may well provide a hint for how to incorporate the phenomenon of metallic conductivity into the model’s current static electride ion picture of metals . Along similar lines, Hooydonk has suggested that bond polarity might also be incorporated into the model using an order–disorder analogy . Also of note is Gillespie’s attempt, in his 1979 Nyholm Lecture, to extend the model to at least a few cluster species of the main-block elements by minimizing core–core repulsions instead of electron-pair repulsions …”
Section: Inherent Limitationsmentioning
confidence: 99%
“…Likewise, Bent has generated a list of interesting parallels between the Kimball model for covalent species and packing models for ionic solids. , Not included in this list, however, is how the ionic model deals with so-called defect structures, though pursuit of this particular analogy may well provide a hint for how to incorporate the phenomenon of metallic conductivity into the model’s current static electride ion picture of metals . Along similar lines, Hooydonk has suggested that bond polarity might also be incorporated into the model using an order–disorder analogy . Also of note is Gillespie’s attempt, in his 1979 Nyholm Lecture, to extend the model to at least a few cluster species of the main-block elements by minimizing core–core repulsions instead of electron-pair repulsions …”
Section: Inherent Limitationsmentioning
confidence: 99%