Boosting ultra-deep hydrodesulfurization of diesel by tuning sulfidation degree of metals on NiMo/AlOOH catalyst

Meng, Xin-Yu; Zhao, Yiyi; Peng, Chong; Liu, Peng; Men, Yu-Long; Pan, Yun-Xiang

doi:10.1016/j.ces.2024.119718

Chemical Engineering Science

2024

DOI: 10.1016/j.ces.2024.119718

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Boosting ultra-deep hydrodesulfurization of diesel by tuning sulfidation degree of metals on NiMo/AlOOH catalyst

Xin-Yu Meng,

Yiyi Zhao,

Chong Peng

et al.

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Cited by 6 publications

References 43 publications

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Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂

Liu,

Meng,

Wang

et al. 2024

AIChE Journal

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Supported metal catalysts have been widely applied and commonly fabricated through the H2 reduction process. Herein, we develop a H2‐free room‐temperature discharge‐driven reduction (RT‐DR) reactor for fabricating supported metal catalysts at room temperature without H2. By RT‐DR reactor, a catalyst with pseudo‐boehmite (PB) as support (CdS/Pt/PB) is fabricated. In visible‐light‐driven photocatalytic H2O splitting to H2, CdS/Pt/PB shows a H2 evolution rate of 1132 μmol h−1, which is greatly enhanced than that on catalyst prepared by traditional H2‐reduction (633 μmol h−1). RT‐DR reactor is also used to prepare a catalyst with low sodium PB (LSPB) as support (CdS/Pt/LSPB). In visible‐light‐driven photocatalytic H2O splitting to H2, CdS/Pt/LSPB shows a H2 evolution rate of 2554 μmol h−1, which is 2.5 times higher than that on catalyst prepared by traditional H2‐reduction (1029 μmol h−1). Thus, RT‐DR reactor has high efficiency and universality in preparing catalysts, thus offering a great potential for commercialization.

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Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂

Liu,

Meng,

Wang

et al. 2024

AIChE Journal

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Selectivity modulation in Fischer-Tropsch synthesis through reducibility control of cobalt-species containing HMS framework

Zepeda

2025

Catalysis Today

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The regulatory role of cysteine in active phase construction of polyoxometalate-based hydrodesulfurization catalysts: Reduction, chelation, and dispersion

Zhang,

Bao,

Yue

et al. 2024

Chemical Engineering Science

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Boosting ultra-deep hydrodesulfurization of diesel by tuning sulfidation degree of metals on NiMo/AlOOH catalyst

Cited by 6 publications

References 43 publications

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂

Selectivity modulation in Fischer-Tropsch synthesis through reducibility control of cobalt-species containing HMS framework

The regulatory role of cysteine in active phase construction of polyoxometalate-based hydrodesulfurization catalysts: Reduction, chelation, and dispersion

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Boosting ultra-deep hydrodesulfurization of diesel by tuning sulfidation degree of metals on NiMo/AlOOH catalyst

Cited by 6 publications

References 43 publications

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H2

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H2

Selectivity modulation in Fischer-Tropsch synthesis through reducibility control of cobalt-species containing HMS framework

The regulatory role of cysteine in active phase construction of polyoxometalate-based hydrodesulfurization catalysts: Reduction, chelation, and dispersion

Contact Info

Product

Resources

About

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂

Discharge reactor for fabricating efficient supported metal catalysts at room temperature in the absence of H₂