Borane-Tetrahydrofuran

Zaidlewicz, M.; Brown, Herbert C.; Neelamkavil, Santhosh

doi:10.1002/047084289x.rb241.pub2

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2023

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“… 46 The borane moiety present in the structure of CORM-A1, as well as the previously published mechanism of CO release, permits the assumption that the by-product is boric acid, given that borane, the only remaining component after CO release, produces boric acid and hydrogen gas when in aqueous solution. 47 The production of boric acid from borane in aqueous solution is an intrinsic redox reaction. Based on the CO release mechanism in Scheme 1 , it is reasonable that the transformation from CORM-A1 to iCORM-A1 is analogous to this redox reaction.…”

Section: Resultsmentioning

confidence: 99%