Borataalkenes, boraalkenes, and the η<sup>2</sup>-B,C coordination mode in coordination chemistry and catalysis

Eaton, Maxwell; Zhang, Yuanzhe; Liu, Shih-Yuan

doi:10.1039/d3cs00730h

Chem. Soc. Rev.

2024

DOI: 10.1039/d3cs00730h

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Borataalkenes, boraalkenes, and the η²-B,C coordination mode in coordination chemistry and catalysis

Maxwell Eaton,

Yuanzhe Zhang,

Shih-Yuan Liu

Abstract: This review summarizes the recent advances in the synthesis of transition metal borataalkene and boraalkene complexes, and the η2-B,C coordination mode in homogeneous catalysis.

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Boron‐Nitrogen‐Containing Benzene Valence Isomers

Ozaki,

Liu

2024

Chemistry A European J

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Benzene is one of the most ubiquitous structural motifs in chemistry. The valence isomers of benzene have also attracted synthetic chemists’ attention due to their unique structures, bonding, and reactivity. We have been investigating boron‐nitrogen‐containing benzene valence isomers via photoisomerization of 1,2‐azaborines. In this contribution, we summarize recent developments of these highly strained BN‐heterocyclic compounds including their synthesis, characterization, proposed mechanism of formation, and their potential applications.

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Boron‐Nitrogen‐Containing Benzene Valence Isomers

Ozaki,

Liu

2024

Chemistry A European J

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Organocatalytic Asymmetric Allylic Benzylborylation via Fluoride-Assisted Catalytic Generation of α-Boryl Carbanionic Intermediates

Duran,

Rodríguez,

Vermeer

et al. 2024

Org. Lett.

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Herein we describe the organocatalytic asymmetric allylic benzylborylation of allyl fluorides with α-silyl benzylboronic esters. The catalytic protocol leverages the singular features of fluoride as an unconventional leaving group, enabling the catalytic generation of reactive α-boryl carbanion species through desilylative activation. It allows the construction of a wide set of homoallylic benzylated organoboronates bearing two contiguous stereocenters. The chiral boronate installed in the products serves as a synthetic lynchpin to construct complex chemical architectures in a stereospecific manner.

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Borataalkenes, boraalkenes, and the η²-B,C coordination mode in coordination chemistry and catalysis

Abstract: This review summarizes the recent advances in the synthesis of transition metal borataalkene and boraalkene complexes, and the η2-B,C coordination mode in homogeneous catalysis.

Cited by 2 publications

References 117 publications

Boron‐Nitrogen‐Containing Benzene Valence Isomers

Boron‐Nitrogen‐Containing Benzene Valence Isomers

Organocatalytic Asymmetric Allylic Benzylborylation via Fluoride-Assisted Catalytic Generation of α-Boryl Carbanionic Intermediates

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Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis

Abstract: This review summarizes the recent advances in the synthesis of transition metal borataalkene and boraalkene complexes, and the η2-B,C coordination mode in homogeneous catalysis.

Cited by 2 publications

References 117 publications

Boron‐Nitrogen‐Containing Benzene Valence Isomers

Boron‐Nitrogen‐Containing Benzene Valence Isomers

Organocatalytic Asymmetric Allylic Benzylborylation via Fluoride-Assisted Catalytic Generation of α-Boryl Carbanionic Intermediates

Contact Info

Product

Resources

About

Borataalkenes, boraalkenes, and the η²-B,C coordination mode in coordination chemistry and catalysis