Boron, aluminium, gallium, indium and thallium

Johnson, Andrew L.; Kresiński, Roman A.; López, César A.

doi:10.1039/b612601b

Cited by 4 publications

(1 citation statement)

References 302 publications

(295 reference statements)

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“…By examining the IR spectrum of the heteroleptic complex it is observed that the occurring bands are typical of bis(dithiolene) nickel complexes, [29] with the most characteristic ν CN band observed at 2202 cm -1 , found at approximately 5 cm -1 less than the same band observed for the symmetrical complex 4 -. Stretch ν C=C values are found at the region of 1450-1470 cm -1 , and ν C-S are observed at ≈ 1173 and 883 cm -1 .…”

Section: Synthesis and Characterization Of Heteroleptic Dithiolene Comentioning

confidence: 87%

Establishing Structure–Activity Relationships in Photocatalytic Systems by Using Nickel Bis(dithiolene) Complexes as Proton Reduction Catalysts

et al. 2019

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Herein, we present an artificial photocatalytic system for H2 evolution based on a series of proton reduction catalysts, namely [Ni{S2C2(Ph)2}2] (1), [Ni{S2C2(Ph)2}2](NEt4) (1–), [Ni{S2C2(Ph)(Ph–OCH3‐4)}2] (2), [Ni{S2C2(Ph)(Ph–OCH3‐4)}2](NEt4) (2–), [Ni{S2C2(Ph–OCH3‐4)2}2] (3) and [Ni{S2C2(Ph–OCH3‐4)2}2](NEt4) (3–), [Ni(mnt)2] (NBu4) (4–), [Ni(mnt)(S2C2(Ph)2)](NBu4) (5–). These complexes are different of both in charge and the substituents on dithiolene ligand and represent a group of active catalysts for the reduction of protons with high TONs. A series of ReI complexes, [ReBr(CO)3 (bpy)], [ReCl(CO)3(bpy)], [Re(NCS)(CO3)(bpy)], [ReBr(CO)3(amphen)] and [ReBr(CO)3 (pq)] were used as photosensitizers, in combination with triethanolamine as a sacrificial electron donor and acetic acid as a proton source. The differences of the ligands in the electron donating properties and reactivity are discussed in the light of the experimental data. We also present the physicochemical characterization of a previously reported heteroleptic monoanionic complex (5–), by UV/Vis spectroscopy, FTIR spectroscopy, cyclic voltammetry and single‐crystal X‐ray diffraction studies.

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Section: Synthesis and Characterization Of Heteroleptic Dithiolene Comentioning

confidence: 87%

Establishing Structure–Activity Relationships in Photocatalytic Systems by Using Nickel Bis(dithiolene) Complexes as Proton Reduction Catalysts

et al. 2019

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Gallium: Inorganic Chemistry

Banger

2015

Encyclopedia of Inorganic and Bioinorganic Chemistry

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This article is based on the original article written by Barron et al ., which provides an overview of the inorganic chemistry of gallium and its compounds. While the structure has remained the same, the sections have been updated to include areas of current studies in this field. In addition, the use of various Ga‐related alloys as either binary or ternary semiconducting material for bulk, thin film, and nanotechnology is reported. The chemistry of Ga inorganic and coordination derivatives is also reviewed and discussed.

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