Boron annual survey covering the year 1977 Part II

Niedenzu, K.

doi:10.1016/s0022-328x(00)92304-0

Journal of Organometallic Chemistry

1978

DOI: 10.1016/s0022-328x(00)92304-0

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Boron annual survey covering the year 1977 Part II

K. Niedenzu

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The kinetics of the reaction of boric acid with salicylic acid

Queen¹

1977

Can. J. Chem.

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Salicylic acid forms a 1:1 complex with boric acid, the reaction involving both the fully protonated ligand, and the salicylate ion. The kinetics of this reaction have been studied by the stopped-flow method. The stability constant for the reaction involving salicylate ion has been calculated from measurements of the absorbances of solutions at equilibrium and is the same as that obtained from the kinetic data. The kinetic results at pH values in the range 3.45–4.63 suggest that, when salicylic acid is the ligand, the complex is formed in two steps. A similar process may also occur with salicylate ions.

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The kinetics of the reaction of boric acid with salicylic acid

Queen¹

1977

Can. J. Chem.

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Boron annual survey covering the year 1977 Part II

Cited by 1 publication

References 250 publications

The kinetics of the reaction of boric acid with salicylic acid

The kinetics of the reaction of boric acid with salicylic acid

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