2022
DOI: 10.1021/acsapm.2c00060
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Boron Cage Triggered Micellization of a Neutral–Cationic Block Copolymer and Preparation of Boron-Containing Layer-by-Layer Microparticles

Abstract: The preparation of a polymer carrier for a boron delivery agent is presented through a combination of experimental and computational studies. A dodecahydro-closo-dodecaborate (B12H12)2– (B12) anion was used as a model boron-containing agent due to its high boron content. Quaternized poly­(2-vinyl pyridine)-b-poly­(ethylene oxide) (QP2VP-b-PEO) was chosen as a model neutral–cationic block copolymer to construct the carrier. The electrostatic association between QP2VP and B12 induced the self-assembly of QP2VP-b… Show more

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