The ramjet engine has undergone rapid development in recent decades, and the dual combustion chamber ramjet (DCR) engine was proposed in the last century. Boron, with its high volumetric and gravimetric heating values, is one of the most attractive fuel additives for ramjet engines. However, due to the problem of low combustion efficiency, boron is difficult to achieve high efficiency combustion in practical applications. In order to investigate the combustion characteristics of boron-containing gas solid phase components in DCR engines, the Realizable k-ε model, finite rate/vortex dissipation model and boron particle King model ignition combustion calculation program were written. A three-dimensional full-scale two-phase flow numerical simulation was carried out in the combustion chamber of the DCR engine to calculate the effects of different particle sizes on the combustion characteristics. Through the analysis of the simulation results, the particle size affects the ignition time of boron particles and is positively correlated with the combustion efficiency, but with a non-linear growth. A smaller particle size can promote the ignition of boron particles, improve the solid phase combustion efficiency and achieve efficient combustion.