Electrification is an efficient way to decarbonize by replacing fossil fuels with low-emission power. In addition, energy efficiency measures can reduce consumption, making it easier to shift to a zero-carbon society. In Québec, upgrades to aging buildings that employ electric resistance heating offer a unique opportunity to free up large amounts of hydroelectricity that can serve to decarbonize heating in other buildings. However, another source of energy would be needed to electrify mobility because efficiency measures free up small amounts of electricity in summer compared to winter. This study reveals how building efficiency measures combined with solar electricity generation provide an energy profile that matches the requirements for decarbonizing both mobility and heating. The TRNSYS software was used to simulate the annual energy performance of an existing house and retrofitted/rebuilt low-energy houses equipped with a photovoltaic (PV) roof in Montreal, Québec, Canada (45.5° N). The electricity that is made available by upgrading the houses is mainly considered for powering battery and fuel cell electric vehicles (BEVs and FCEVs) and electrifying heating in greenhouses. The results indicate that retrofitting 16% or rebuilding 12% of single-detached homes in Québec can provide enough electricity to decarbonize heating energy use in existing greenhouses and to operate the new greenhouses required for growing all fresh vegetables locally. If all the single-detached houses that employ electric resistance heating are upgraded, 33.4 and 21.8 TWh year−1 of electricity would be available for decarbonization, equivalent to a 19% and 12% increase of the province’s electricity supply for the retrofitted or rebuilt houses, respectively. This is enough energy to convert 83–100% of personal vehicles to BEVs or 35–56% to FCEVs. Decarbonization using the electricity that is made available by upgrading to low-energy solar houses could reduce the province’s greenhouse gas (GHG) emissions by approximately 32% (26.5 MtCO2eq). The time required for the initial embodied GHG emissions to surpass the emissions avoided by electrification ranges from 3.4 to 11.2 years. Building energy efficiency retrofits/rebuilds combined with photovoltaics is a promising approach for Québec to maximize the decarbonization potential of its existing energy resources while providing local energy and food security.