2019
DOI: 10.1002/celc.201900702
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Bottom‐Up Characterization and Self‐Assembly of Electrogenerated Chemiluminescence Active Ruthenium Nanospheres

Abstract: An approach to electrogenerated chemiluminescence (ECL) signal enhancement, utilizing the highly tailorable ring‐opening metathesis polymerization (ROMP) to generate novel ECL active nanoscale structures is explored. The strategy involves integrating into a single polymer multiple copies of an analogue of the established ECL luminophore, tris(2,2’‐bipyridine)ruthenium(II) (Ru(bpy)32+). Through the addition of hydrophobic and hydrophilic functional groups to the polymer architecture, these ECL active block copo… Show more

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References 38 publications
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