With simulation and experiment we examine the effect of grain anisotropy on the angle of repose in a two-dimensional geometry. We find that the structure of the granular packing can be directly controlled by changing the aspect ratio of the grains, and that the specific type of order strongly affects the angle of repose and the resulting dynamics. The angle of repose is largest for dimer grains, and is smaller for both monomer and trimer grains. The motion of a collapsing grain heap consists of large scale collective shear when monomer grains are considered, but occurs via tumbling of grains on the surface for dimers, and via disorderly bulk tumbling for trimer grains. PACS numbers: 45.70. Mg, 81.05.Rm, Granular assemblies have attracted much recent attention since they are a model system in which collective nonequilibrium dynamics, compaction, pattern formation, frustration, nonlinear flows, and jamming can be readily examined [1]. The behavior they display is relevant to a diverse array of physical systems, including powders, colloids, liquids, and vortex matter in superconductors. In addition, an understanding of granular mechanics will be valuable for increasing the efficiency of a wide range of industrial processes and applications. A fundamental question that arises is the relation between the mechanical response of the granular media and the ordering of the individual grains. The nature of the closepacked ordering in 3D of different types of granular media is itself an open issue. In this work we study a simple system of granular assemblies confined in a 2D plane and show that specific types of ordering can be controllably produced by tuning the anisotropy of the grains. The resulting structure of the granular pack has a profound effect on the angle of repose and the granular dynamics.Most previous work on the effects of grain geometry has focused on angles of repose for grains that are roughly spherical. The effect of dispersion in the sizes of individual spherical grains has been considered [2], as well as the effect of varying the roughness of the grain surface [3] or of having nonspherical grains [4,5]. Anisotropic or elongated grains have attracted interest previously, but it has generally been in the context of the flow of feed grains through a hopper [6]. Only one systematic study has considered the effect of gradual elongation of the grains on the angles of repose. In Ref.[5], it was observed that as the grain is elongated continuously from a monomer to a dimer, the angle of repose increases monotonically. The grain shape was continuously varied, so it would not be possible to form an ordered lattice with the same lattice constant using any two grain geometries considered.In this work we consider with experiments and simulations a system composed of grains that can always be packed into a triangular lattice of monomers, but are individually composed of monomers, dimers, or trimers. Some previous simulation studies have focused on fully three-dimensional systems [7,8]. This introduces considerable ...