Observing how electronic states in solids react to a local symmetry breaking provides insight into their microscopic nature. A striking example is the formation of bound states when quasiparticles are scattered off defects. This is known to occur, under specific circumstances, in some metals and superconductors but not, in general, in the charge-density-wave (CDW) state. Here, we report the unforeseen observation of bound states when a magnetic field quenches superconductivity and induces long-range CDW order in YBa2Cu3Oy. Bound states indeed produce an inhomogeneous pattern of the local density of states N (EF ) that leads to a skewed distribution of Knight shifts which is detected here through an asymmetric profile of 17 O NMR lines. We argue that the effect arises most likely from scattering off defects in the CDW state, which provides a novel case of disorder-induced bound states in a condensed-matter system and an insightful window into charge ordering in the cuprates.Recent experiments in high-T c copper-oxides at moderate doping levels have led to a consensus regarding the presence of static, but essentially short-range, spatial modulations of the charge density that appear far above the critical temperature T c and compete with superconductivity below T c [1, 3,[3][4][5][6][7][8][9][10][11][12]. As a result, the debate has mainly focused on this "incipient" charge-density-wave (CDW) in zero magnetic field. Somewhat less attention has been paid to another CDW order that also coexists and competes with superconductivity but is present at lower temperatures, only in high magnetic fields, and has been detected only in YBa 2 Cu 3 O y (YBCO) so far, by nuclear magnetic resonance (NMR) [1,13] and more recently by X-ray diffraction [2,15]. This CDW develops long-range three-dimensional (3D) correlations above a critical field (also detected in sound velocity [17] and thermal conductivity measurements [18]). In principle, the long-range coherence of the high-field CDW makes it a unique playground for investigating the nature of CDW order in cuprates and its interplay with superconductivity [19]. However, since its observation requires high fields, experimental characterization of this phase has remained limited. This evidently prompts for further high field experiments in YBCO.Here, we report that a spatial distribution of 17 O Knight shift values develops alongside with the high-field CDW in YBCO. After discarding broadening by the vortex lattice or magnetic order, we explain the effect by an enhancement of N (E F ), the local density-of-states (LDOS) at the Fermi energy E F , due to the formation of quasiparticle bound states as observed around defects in the superconducting state of cuprates [5,[20][21][22][23][25][26][27]. This unforeseen observation raises fundamental questions on the electronic band structure and the nature of defects in the CDW state.17 O-enriched untwinned single crystals of YBa 2 Cu 3 O y were prepared with y nominal = 6.47 (ortho-II oxygen ordering, hereafter O-II), 6.56 (O-II), 6.68 (O...