We have measured the beta-decay branching ratio for the transition from 21 Na to the first excited state of 21 Ne. A recently published test of the standard model, which was based on a measurement of the β-ν correlation in the decay of 21 Na, depended on this branching ratio. However, until now only relatively imprecise (and, in some cases, contradictory) values existed for it. Our new result, 4.74(4)%, reduces but does not remove the reported discrepancy with the standard model.