Electron transport coefficients in copper vapor plasma are calculated both by two-term expansion of electron Boltzmann equation Bolsig+ and tracking the random motion of electrons using Monte Carlo collision code METHES based upon recently evaluated cross section sets. The copper atoms are evaporated from hot electrode during the post-arc phase of vacuum circuit breakers, in which Townsend breakdown between electrode gaps is probable. The electron energy probability function, electron mean energy, flux/transport mobility and diffusion coefficients, as well as Townsend ionization coefficients are shown in reduced fields 10∼1000 Td at a typical vapor temperature 2000 K. The validity of two-term approximation is checked by comparison to well benchmarked METHES code. If the electrode temperature varies between 1500∼2500 K, the influence of vapor temperature on ionization coefficients is about 5% at 200.4 Td, and drops to 0.5% at 493 Td according to Bolsig+ results. Similar to classic gas discharge theory, the Paschen curve is proposed for Townsend breakdown of metal vapor. Using the calculated ionization coefficient and a constant secondary electron yield, the Paschen minimum is determined to be 106∼122 V at a critical value of the product of vapor density and gap length (4.7∼5.7)×1019 m-2. A satisfactory agreement was found with the previously measured ignition voltage between vacuum interrupter contacts after the arcing.