The dynamic behavior of highly oriented ferroelectric Sr 1.9 Ca 0.1 NaNb 5 O 15 thin films has been investigated by Brillouin light scattering over a wide temperature range between 25 and 450 • C. The temperature variations of the full-width at half-maximum (FWHM) of the central peak (CP) are found to exhibit marked changes around the Curie temperature (T c = 246 • C). The CP reveals a relaxational mode behavior, which is attributed to thermally activated fast relaxation of polar nanoregions (PNRs). The width of the CP decreases steadily upon cooling from ∼400 • C to T c and shows little subsequent change within the ferroelectric state, indicating an increase of the number of PNRs and a slowing down of their dynamics. By using a modified superparaelectric model, the activation energy (H 0 ) of the relaxation processes and the Burns temperature (T B ) are determined to be 2939 and 385 • C, respectively. The evidence for this diffuse phase transition provided by Brillouin scattering is in agreement with results obtained from the temperature-dependent dielectric permittivity, refractive index, and Raman spectra.