The elastic and vibrational properties of a material, bulk or planar waveguide, are studied by Brillouin and Raman spectroscopy to follow the process of nanocrystals growth in glass-ceramics. The nanoparticles cause the appearance, in the low frequency Raman spectrum, of characteristic peaks, whose position depends on the size of the crystals. At the same time, sharp crystal peaks, due to optical phonons, appear in the Raman spectra, allowing the determination of the nucleated phase, and a frequency shift of the Brillouin peaks is observed. CLC numbers: TB383 Document code: A Article ID: 1673-1905(2007)03-0188-04 DOI Brillouin and Raman spectroscopies (BS and RS), by exploiting the interaction between light and vibrations, are powerful non-destructive techniques extensively used in pure and applied research to characterize materials. Systems in different state of aggregation, liquids, solids and gases can be studied by RS and BS [1][2][3][4][5][6][7] . Also, single molecules have been studied by surface enhanced Raman scattering [8] . The Raman and Brillouin spectra give information on the structure of crystals, glasses and glass-ceramics, show the nature of bonds and give insight on the elastic inhomogeneities caused by pores, nanoparticles and phase separation on various length scales [1,2,6] . In particular RS is a very useful analytic tool, since the vibrating molecular groups (Raman active) have characteristic frequencies.The analysis is also quantitative, the scattered light being proportional to the concentration of such groups.In optoelectronics, these investigation techniques are widely used both for characterizing crystals, as, for instance, to assess the stoichiometry of LiNbO3 with high resolution [9] , or glasses. RS constitutes the main technique to investigate the structure of glasses, lacking the information that Xray diffraction may give for crystals. RS with waveguided excitation in a mode of a planar waveguide (WG) has the advantage of obtaining information only on the region of interest, avoiding the contribution of the substrate. Moreover, in a graded index WG, different guided modes propagate at different depths in the guiding film leading to a depth-selective spectroscopic characterization of a WG by RS and BS [10,13] .In a light scattering experiment, the spectral density of the scattered light is given bywhere q and are the exchanged wavevector and energy, respectively and is the fluctuation of the dielectric constant. The inelastic light scattering is due to time dependent dielectric constant fluctuations [2,12] . The fluctuations of the dielectric constant may be due to the change of the position of the scatter units and to a change of their polarizabilities, induced by the vibration. This allows to roughly distinguish the different parts of the scattered light spectrum.BS refers to the light scattered by a propagating acoustic wave, is qdependent, and is mainly caused by the displacements of the scatterers. RS refers to optical vibrations, is practically qindependent, and is mainly cau...