A novel customized π-shaped split-ring resonator metasurface arranged in two configurations is presented to decouple 1×2 and 1×4 Millimeter-Wave (MMW) Magneto-Electric (ME) Dipole in the H-Plane with 1.6 mm (0.32λ at 60 GHz) inter-element spacing. The metamaterial unit cell is first designed to inhibit the propagation of coupled surface waves within the bandwidth of interest. A 5×2 arrangement of this unit cell is carefully positioned on the top and bottom of the superstrate with 1 mm spacing (0.2λ at 60 GHz) between the antenna and the superstrate. In the 1×2 array, a maximum measured mutual coupling reduction of 53 dB is observed within the 52-66 GHz bandwidth (23.7%). To further demonstrate the uniqueness of the metasurface, an 11×2 configuration of this unit cell is arranged as a superstrate for the 1×4 ME-dipoles. A maximum measured mutual coupling reduction of 40 dB is achieved without a considerable effect on the radiation characteristics. Parametric analysis is performed to confirm the uniqueness of this new decoupling structure. The proposed antenna exhibits measured high total efficiency (> 89%), high gain (> 8 dB), low envelope correlation coefficient (<0.0003), and very good radiation characteristics throughout the entire bandwidth. The fabricated prototype antenna is measured to validate the simulation results. The proposed antenna is a good recommendation for V-band millimeter-wave MIMO applications like radar research.INDEX TERMS Millimeter-wave magneto-electric dipole, multiple-input-multiple-output (MIMO), split ring resonator.