Broadband ultrafast-laser-absorption imaging in the ultraviolet for spatiotemporally resolved measurements of temperature and CN

Abstract

This Letter describes the development and implementation of an ultraviolet and broadband ultrafast-laser-absorption-imaging (UV-ULAI) diagnostic for one dimensional (1D) imaging of temperature and CN via its [Formula: see text] absorption bands near 385 nm. The diagnostic was demonstrated by acquiring single-shot measurements of 1D temperature and CN profiles in HMX flames at a repetition rate of 25 Hz. Ultrashort pulses (55 fs) at 800 nm were generated using a Ti:Sapphire oscillator and then amplification and wavelength conversion to the ultraviolet were carried out using an optical parametric amplifier and frequency doubling crystals. The broadband pulses were spectrally resolved using a 1200 l/mm grating and imaged on an EMCCD camera to obtain CN absorbance spectra with a resolution of [Formula: see text]0.065 nm and a bandwidth of [Formula: see text]4 nm (i.e., 260 cm–1). Simulated absorbance spectra of CN were fit to the measured absorbance spectra using non-linear curve fitting to determine the gas properties. The spatial evolution of gas temperature and CN concentration near the burning surface of an HMX flame was measured with a spatial resolution of [Formula: see text]10 μm. 1D profiles of temperature and CN concentration were obtained with a 1- σ spatial precision of 49.3 K and 4 ppm. This work demonstrates the ability of UV-ULAI to acquire high-precision, spatially resolved absorption measurements with unprecedented temporal and spatial resolution. Furthermore, this work lays the foundation for ultraviolet imaging of numerous atomic and molecular species with ultrafast time resolution.