Diffusion and transport phenomena can be explained by deterministic models involving ordinary or partial differential equations, and Brownian motion has been a popular model for simulating random physical processes. The real dynamics of Brownian motion, however, can be better presented in terms of stochastic or probabilistic models. A Basic program named RWALK, which stands for "random walk", has been written to simulate diffusion processes by a simple yet powerful mathematical tool known as a stochastic differential equation. By entering the initial value, drift, standard deviation (which is related to diffusion coefficient), and periods to be simulated, a student can generate various sample paths or trajectories with this program. A simple and economical exercise to model a student's wrist pulse has been devised. All suggested activities can be done in one normal laboratory period, and the simulation exercises with RWALK should give students in physical chemistry a concrete command over an abstract topic like Brownian motion as well as some exposure to basic statistical concepts using a spreadsheet or a commercial statistical software.