A double stage AC/DC sequential high voltage reactor has been developed to study the decomposition of benzene in the air stream at atmospheric pressure. The removal efficiency was measured as a function of ozonation, flow recycling, and flow recirculation. Ozonation in the inlet, and recycling of the exhaust stream increased the removal of benzene, also with increasing of specific input energy (J l −1 ) the effect of inlet flow ozonation on benzene decomposition was enhanced. The highest removal efficiency was obtained up to >99% in recirculation six times, while CO 2 selectivity reached 99.9% and energy efficiency was 0.59 g kWh −1 . O 3 production/ decomposition > production of OH radicals > electronic and ionic collisions were indicated as the main mechanisms influencing benzene abatement in this research.