Wireless technologies are being introduced in industrial applications since they provide certain benefits, such as the flexibility to modify the layout of the nodes, improving connectivity with monitoring and decision nodes, adapting to mobile devices and reducing or eliminating cabling. However, companies are still reluctant to use them in time-critical applications, and consequently, more research is needed in order to be massively deployed in industrial environments. This paper goes in this direction by presenting a novel wireless acquisition system aimed at industrial applications. This system embeds a low-cost technology, such as XBee, not frequently considered for deterministic applications, for deploying industrial applications that must fulfill certain QoS requirements. The use of XBee 900 MHz modules allows for the use of the 2.4 GHz band for other purposes, such as connecting to cloud services, without causing interferences with critical applications. The system implements a time-slotted media access (TDMA) approach with a timely transmission scheduling of the messages on top of the XBee 900 MHz technology. The paper discusses the details of the acquisition system, including the topology, the nodes involved, the so-called coordinator node and smart measuring nodes, and the design of the frames. Smart measuring nodes are implemented by an original PCB which were specifically designed and manufactured. This board eases the connection of the sensors to the acquisition system. Experimental tests were carried out to validate the presented wireless acquisition system. Its applicability is shown in an industrial scenario for monitoring the positioning of an aeronautical reconfigurable tooling prototype. Both wired and wireless technologies were used to compare the variables monitored. The results proved that the followed approach may be an alternative for monitoring big machinery in indoor industrial environments, becoming especially suitable for acquiring values from sensors located in mobile parts or difficult-to-reach places.