Heat and mass transfer by natural convection coupled to wall surface condensation or evaporation in a two-dimensional cavity subjected to uniform, but time-dependent wall temperatures is investigated numerically. At initial state, the cavity is filled with quiescent humid air at uniform temperature and density. By decreasing the wall temperature, condensation occurs at the four wall surfaces until an equilibrium thermodynamic state is reached. The walls are then Ra m solutal Rayleigh number,Sh local Sherwood number (Eq. 36)Greeks β m solutal coefficient of volumetric expansion