2007
DOI: 10.1007/s00217-007-0724-7
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Butter and butter oil classification by PTR-MS

Abstract: The potential of proton transfer reaction mass spectrometry (PTR-MS) as a tool for classification of milk fats was evaluated in relation to quality and authentication issues. Butters and butter oils were subjected to heat and off-flavouring treatments in order to create sensorially defective samples. The effect of the treatments was evaluated by means of PTR-MS analysis, sensory analysis and classical chemical analysis. Subsequently, partial least square-discriminant analysis models (PLS-DA) were fitted to pre… Show more

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Cited by 45 publications
(25 citation statements)
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“…All mass peaks found significantly different at least in one of the time point ( P < .01) were reported by starting from m / z = 41.038 and by taking a concentration threshold of at least 0.1 ppbV. Twenty‐eight mass peaks were tentatively identified on the basis of their sum formula, fragmentation pattern, and literature data …”
Section: Resultsmentioning
confidence: 99%
“…All mass peaks found significantly different at least in one of the time point ( P < .01) were reported by starting from m / z = 41.038 and by taking a concentration threshold of at least 0.1 ppbV. Twenty‐eight mass peaks were tentatively identified on the basis of their sum formula, fragmentation pattern, and literature data …”
Section: Resultsmentioning
confidence: 99%
“…In addition, this technique does not require any sample pre-treatment such as drying or pre-concentration and is thus well suited for oxygenated VOCs, which cannot be quantified from canister samples used in a traditional chemical analysis method. PTR-MS has been widely used in atmospheric, food, environmental science, forensic investigation and medical research (Blake et al, 2009;Boscaini et al, 2004;Filella and Penuelas, 2006;de Gouw and Warneke, 2007;Granitto et al, 2007;Hewitt et al, 2003;Jobson et al, 2005;Kato et al, 2004;Lindinger et al, 1998Lindinger et al, , 2001Lindinger et al, , 2008Lirk et al, 2004;Mayr et al, 2003;Steeghs et al, 2004;Van Ruth et al, 2007;Wang and Stout, 2007;Warneke et al, 2003;Wehinger et al, 2007;Whyte et al, 2007). On the other hand, there have been rare studies in the field of indoor air quality utilizing this technique with a few exceptions (Bunge et al, 2008;Fang et al, 2008;Weschler et al, 2007;Wisthaler et al, 2007).…”
Section: Introductionmentioning
confidence: 99%
“…The application of this technique usually leads to a fingerprint of the emission of VOCs profile from food samples for the study of quality, fermentation, ripening, and processing. As an example, PTR-MS has been used to investigate volatile fingerprints of orange juices subjected to different thermal and pressure treatments [35], classification of milk fats of different qualities [36], prediction of freshness of bread [37], classification of infant formulas according to different brands and physical forms [38], and prediction of sensory profiles of coffee [39]. Special importance has been given to wine [40,41] owing to the economic importance of this industry.…”
Section: Direct Apci-hrms and Ptr-hrmsmentioning
confidence: 99%