2024
DOI: 10.1021/acs.inorgchem.4c01993
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C(sp)–H, S–H, and Sn–H Bond Activation with a Cobalt(I) Pincer Complex

Sayantani Saha,
Jeanette A. Krause,
Hairong Guan

Abstract: This study focuses on the stoichiometric reactions of {2,6-( i Pr2PO)2C6H3}­Co­(PMe3)2 with terminal alkynes, thiols, and tin hydrides as part of an effort to develop catalytic, two-electron processes with cobalt. This specific Co­(I) pincer complex proves to be effective for cleaving the C­(sp)–H, S–H, and Sn–H bonds to give oxidative addition products with the general formula {2,6-( i Pr2PO)2C6H3}­CoHX­(PMe3) (X = alkynyl, thiolate, and stannyl groups) along with the free PMe3. These reactions typically reac… Show more

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