(C₆H₁₅N₃)_1.3(NH₄)_1.5H_1.5In₃SnS₈: a layered metal sulfide based on supertetrahedral T2 clusters with photoelectric response and ion exchange properties

Abstract

A new layered metal sulfide, namely (C6H15N3)1.3(NH4)1.5H1.5In3SnS8 (1, C6H15N3 = N-(2-aminoethyl) piperazine), has been solvothermally synthesized and characterized. Compound 1 crystallizes in the monoclinic space group C2/c. Its structure features...