2022
DOI: 10.1002/zaac.202100342
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Ca2Ga4Ge6 and Ca3Ga4Ge6: Synthesis, Structure, and Electronic Properties

Abstract: Dedicated to Mercouri Kanatzidis in celebration of his 65 th birthday. During the search for transition metal-free alkyne hydrogenation catalysts, two new ternary CaÀ GaÀ Ge phases, Ca 2 Ga 4 Ge 6 (Cmc2 1 , a = 4.1600(10) Å, b = 23.283(5) Å, c = 10.789(3) Å) and Ca 3 Ga 4 Ge 6 (C2/m, a = 24.063(2) Å, b = 4.1987(4) Å, c = 10.9794(9) Å, β = 91.409( 4)°), were discovered. These compounds are isostructural to the previously established Yb 2 Ga 4 Ge 6 and Yb 3 Ga 4 Ge 6 analogues, and according to Zintl-Klemm count… Show more

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