Cadmium(II) chloride complexes of imidazole-based ligands: Solvothermal syntheses, crystal structures and luminescent properties

Cheng, Chu Yong; Shen, Nannan; Du, Chunyu; Wang, Zi; Lǐ, Jiànróng; Huang, Xiao‐Ying

doi:10.1016/j.inoche.2017.05.011

Cited by 12 publications

(3 citation statements)

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“…The equatorial plane of the complex is constructed by four Cd−N bonds with lengths ranging from 2.340 (3) to 2.360 (2) Å, and the axial positions are occupied by two Cd−Cl bonds (2.6355(7) Å). These data correspond with those observed in [Cd(NCS)2(Vim)4] and [CdCl2(Im)4] (Cheng et al, 2017). The values of the bond angles around Cd(II) ion are close to those expected for a regular octahedral geometry ( Table 2).…”

Section: X-ray Crystal Structuresupporting

confidence: 87%

“…Yilmaz and co-workers have studied surface areas and hydrogen storage capacities of polymeric squaric acid Co(II), Zn(II), and Cd(II) complexes containing vim ligand (Yilmaz et al, 2018). It is also known that the compounds assembled by d 10 metal centre Cd(II) and imidazole or imidazole derivatives ligands are promising candidates for luminescent materials (Cheng et al, 2017). In this contribution, a new coordination compound of Cd(II) ion containing vim ligand and ancillary Cl atom was synthesized.…”

Section: Introductionmentioning

confidence: 99%

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Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Yolcu

2020

Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi

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In this work dichlorotetrakis(1-vinylimidazole)cadmium(II), [CdCl2(vim)4] complex was synthesized using 1vinylimidazole (vim) ligand and CdCl2. The structure of the complex was characterized by FT-IR spectroscopy, thermal analysis (TG, DTG, DTA) and X-ray single crystal studies. In the FT-IR spectrum of the complex, the characteristic peaks (C−H stretch, C=C and C=N vibration bands) of vim were observed. X-ray crystallographic data of the titled complex revealed that vim ligand coordinated to the metal atom via the heterocyclic ring nitrogen atom. The coordination geometry of the Cd(II) central atom is elongated octahedral. Compound crystallized in P21/n space group, and the mononuclear units were weakly linked to each other by C-H⋯Cl hydrogen bonds. It was determined by thermal analysis data that the complex degraded in four steps and total mass loss was 99%.

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Section: X-ray Crystal Structuresupporting

confidence: 87%

Section: Introductionmentioning

confidence: 99%

Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Yolcu

2020

Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi

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“…9,14 However, many researchers focus on cadmium due to its specific photo-physical properties resulting from its unique structures and composition, 15–18 derived from the amiability of this transition metal to establish bonds with several organic ligands simultaneously; there have been several investigations on Cd( ii ) coordination polymers and multinuclear complexes based on different ligands. 16,19,20…”

Section: Introductionmentioning

confidence: 99%

Assembly of a cadmium(ii)-based chiral complex: crystal structure and optical properties for solid state white-light emission applications

Gassara,

Liu,

Guesmi

et al. 2024

Mater. Adv.

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Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Zhou,

Qi,

Liu

et al. 2024

Adv Funct Materials

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Research on organic–inorganic hybrid materials (OIHMs) has experienced explosive growth in the past decades. The diversity of organic components allows for the introduction of various spatial scales, functional groups, and polarities, while inorganic components provide higher hardness, heat resistance, and stability, their flexible combination facilitates the formation of diverse structures. Furthermore, simple and cost‐effective synthesis methods, such as room temperature solution processes and mechanochemical techniques, enable precise control over the materials' properties at different scales, thus achieving adjustable structure–performance relationships. This review will discuss the recent research progress of OIHMs within the field of optoelectronics and related optoelectronic device applications. According to the dimension of inorganic components and the nature of organic–inorganic interface, this review divides OIHMs into four structural categories. The ongoing research has revealed diverse applications for OIHMs in the fields of solar cells, light‐emitting devices, detectors, and memristors. As an outlook, the potential of perovskite and 0D metal halide materials, which are currently the most studied, for enhancing optoelectronic performance and stability is discussed.

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Cadmium(II) chloride complexes of imidazole-based ligands: Solvothermal syntheses, crystal structures and luminescent properties

Cited by 12 publications

References 47 publications

Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties

Assembly of a cadmium(ii)-based chiral complex: crystal structure and optical properties for solid state white-light emission applications

Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

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