“…Therefore, choosing the right analytical method is essential for the accurate determination of caffeine in test samples. There have been numerous reports on the determination of caffeine in coffee samples following different analytical methods: gas chromatography [15,17,18], electrochemical methods such as voltammetry [19], and spectroscopic techniques including nuclear magnetic resonance spectroscopy [20], near infrared [21], high performance liquid chromatography [5,8,22,23], UV-Vis spectroscopy [4,7,24,25] and fluorescence spectroscopy [26]. However, there are only limited reports available on the comparative study of caffeine determination by different analytical methods for a given set of samples [5,23].…”