Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Boumekla, Yougourthen; Xia, Fengxie; Vidal, Lucas Lauar Cortizo; Totée, Cedric; Raynaud, Christophe; Ouali, Armelle

doi:10.1039/d2ob02243e

Org. Biomol. Chem.

2023

DOI: 10.1039/d2ob02243e

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Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Yougourthen Boumekla

Fengxie Xia

Lucas Lauar Cortizo Vidal

et al.

Abstract: A method to reduce aldimines through hydrosilylation is reported. The catalytic system involves calcium triflimide (Ca(NTf2)2) and potassium hexafluorophosphate (KPF6) shown to act in a synergistic manner. The expected amines...

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Synthetic Methods for Alkyl Amines

2023

Methods and Strategies for C–N Bond Formation Reactions

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Nitrogen is one of the most essential elements for life. It has been used to synthesize essential molecules such as amino acids and nucleotides in the construction of life. Consequently, nitrogen-containing compounds have important roles in all fields of chemistry, and in all aspects of life in living organisms. The N-alkylation of amines constitutes one of the most widely applied transformations in synthetic chemistry, but established methods often utilize non-renewable feedstocks and must be adapted for a post-fossil fuel world. This chapter is focused on emerging methodologies for N-alkylation and considers challenges in the applications of amines and the development of sustainable methodologies.

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Synthetic Methods for Alkyl Amines

2023

Methods and Strategies for C–N Bond Formation Reactions

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show abstract

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Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Abstract: A method to reduce aldimines through hydrosilylation is reported. The catalytic system involves calcium triflimide (Ca(NTf2)2) and potassium hexafluorophosphate (KPF6) shown to act in a synergistic manner. The expected amines...

Cited by 1 publication

References 71 publications

Synthetic Methods for Alkyl Amines

Synthetic Methods for Alkyl Amines

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