2023
DOI: 10.1021/acs.iecr.3c01820
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Calcium Looping for Thermochemical Storage: Assessment of Intrinsic Reaction Rate and Estimate of Kinetic/Transport Parameters for Synthetic CaO/Mayenite Particles from TGA Data

Silvia Lo Conte,
Maria Anna Murmura,
Francesca Fratini
et al.

Abstract: Mayenite-supported CaO represents an affordable and safetycompliant candidate material for thermochemical storage processes. We here analyze the thermogravimetric analysis (TGA) performance of synthetic CaO/mayenite micrometric powder under carbonatation/calcination looping and develop a model to interpret and analyze the experimental results. In the experimental campaign, calcination is run at 900 °C, while the carbonatation temperature is varied between 600 and 800 °C. For the carbonatation reaction, a gener… Show more

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Cited by 5 publications
(2 citation statements)
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“…The decrease in particle diameter increased the number and volume of micropores in the material, and the lower surface energy is conducive to the adsorption of oxygen, which improved the adsorption efficiency of the sample. The stable high reduction rate is controlled exclusively by the intrinsic reaction kinetics in that the advancement of the reaction creates an overpressure inside the grain pores …”
Section: Resultsmentioning
confidence: 99%
“…The decrease in particle diameter increased the number and volume of micropores in the material, and the lower surface energy is conducive to the adsorption of oxygen, which improved the adsorption efficiency of the sample. The stable high reduction rate is controlled exclusively by the intrinsic reaction kinetics in that the advancement of the reaction creates an overpressure inside the grain pores …”
Section: Resultsmentioning
confidence: 99%
“…As depicted in Figure S5, increasing the reaction temperature led to an improvement in the apparent CO 2 sorption rates throughout both the kinetically controlled and diffusion-controlled stages of the carbonation process. Particularly in the diffusion-controlled stage, the transport of CO 2 into the CaCO 3 product layer becomes crucial for the carbonation of Ca/Cu composite sorbents, a process known to intensify with rising temperatures. ,, Hence, the improved CO 2 capture performance of CaP–CuA may stem from improvements in both the reaction kinetics and the CO 2 diffusion within the CaCO 3 product layer.…”
Section: Results and Discussionmentioning
confidence: 99%