“… Constant volume energy addition (Brode, 1959) Real gas behaviour and isentropic expansion (CCPS, 2010) Isothermal expansion (Smith et al, 1996) Thermodynamic availability (Crowl, 1991(Crowl, , 1992 Ideal gas behaviour and isentropic expansion (Prugh, 1991) Real gas behaviour and adiabatic irreversible expansion (Planas et al, 2004;Casal and Salla, 2006) Comparative analysis show that all methodologies tend to provide conservative (i.e. high) results, except those based on real gas behaviour and adiabatic irreversible expansion, which give values that are less conservative but more realistic (Bubbico and Marchini, 2008;Laboureur et al, 2014;Hemmatian et al, 2017).…”