We calculate the Kapitza conductance, which is the proportionality coefficient between heat flux and temperature jump at the interface, for two electronic subsystems separated by the interface. We observe that for electronic subsystems in a non-equilibrium state, there should also arise the electrochemical potential jump at the interface. Hence to describe linear transport at the interface we need three kinetic coefficients: interfacial analogs of electric and heat conductances and interfacial analog of the Seebeck coefficient. We calculate these coefficients for the interface between n-type semiconductors. We have found out that the interfacial analog of the Seebeck coefficient for some range of parameters of the considered semiconductors, has a high value of about 10 −3 V/K. Thus this effect has the potential to be used for the synthesis of effective thermoelectric materials.