“…Some of them focused on thermal ionization in the hot cavity [11,22,23], describing the crucial effect of multiple collisions with the walls of the hot cavity, while other papers presented issues such as vapour transport from the bombarded target to the ionizer [24,25] or the release of nuclides from the walls of the ionizer [26,27]. Various shapes of ionizers were considered in the literature; the most popular being tubular [23,[28][29][30], rarely employed spherical or hemispherical [31][32][33], but also conical [34][35][36], and even the most exotic, resembling a kind of mace with spikes [22]. Recently, a cavity having the shape of a flat disc was considered [37], being a case of tubular ionizer characterized by a very small length compared to its diameter, which results in a large number of particle-wall collisions during the particle's travel to the extraction aperture.…”