Calorimetric study of the selected nitroalkane+chloroalkane binary systems

A transitiometric method for determining isobaric thermal expansivity of liquid 1,4-dichlorobutane and 1-bromo-4-chlorobutane as a function of temperature and pressure through calorimetric measurements against pressure is described. Isobaric thermal expansivities of haloalkanes were determined over the temperature range from 273.15 to 423.15 K at pressures up to 200 MPa. Experimental results were used to model the general density scaling-based equation of state and to analyze the pressure−temperature behavior of the thermal expansion coefficient. We confirmed that investigated liquids present a characteristic pressure range in which (∂α P /∂T) P = 0.

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Isobaric Thermal Expansion of Compressed 1,4-Dichlorobutane and 1-Bromo-4-chlorobutane: Transitiometric Results and a Novel Application of the General Density Scaling-Based Equation of State

Chorążewski

Grzybowski

Paluch

2015

Ind. Eng. Chem. Res.

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Calorimetric study of the selected nitroalkane+chloroalkane binary systems

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Isobaric Thermal Expansion of Compressed 1,4-Dichlorobutane and 1-Bromo-4-chlorobutane: Transitiometric Results and a Novel Application of the General Density Scaling-Based Equation of State

Isobaric Thermal Expansion of Compressed 1,4-Dichlorobutane and 1-Bromo-4-chlorobutane: Transitiometric Results and a Novel Application of the General Density Scaling-Based Equation of State

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