The development of high-performance humidity sensors
to cater for
a plethora of applications, ranging from agriculture to intelligent
medical monitoring systems, calls for the selection of a reliable
and ultrasensitive sensing material. A simplistic device architecture,
robust quantification of ambient relative humidity (% RH), and compatibility
with the contemporary integrated circuit technology make a bimodal
(capacitive and resistive) surface-type sensor to be a prominent choice
for device fabrication. Herein, we have proposed and demonstrated
a facile realization of a 5,10,15,20-tetraphenylporphyrinatonickel
(II)–zinc oxide (TPPNi-ZnO) nanocomposite-based bimodal surface-type
% RH sensor. The TPPNi macromolecule and ZnO nanoparticles have been
synthesized by an eco-benign microwave-assisted technique and a thermal-budget
chemical precipitation method, respectively. It is speculated from
the morpohological study that specific surface area improvement, via
the provision of ZnO nanoparticles on micro-pyramidal structures of
TPPNi, may reinforce the sensing properties of the fabricated humidity
sensor. The relative humidity sensing capacitive and resistive characteristics
of the sensor have been monitored in 40–85% relative humidity
(% RH) bandwidth. The fabricated sensor under the biasing conditions
of 1 V of applied bias (
V
rms
) and 500
Hz AC test frequency exhibits a significantly higher sensitivity of
387.03 pF/% RH and 95.79 kΩ/% RH in bimodal operation. The average
values of both the response and recovery times of the capacitive sensor
have been estimated to be ∼30 s. It has also been debated why
this high degree of sensitivity and considerable reduction in response/recovery
time has been obtained. In addition, the intense and wide bandwidth
spectral response of the TPPNi-ZnO nanocomposite indicates that it
may also be utilized as a potential light-harvesting heterostructured
nanohybrid in future studies.