A wake-controlled exterior hood was developed to overcome the negative influence of cross draft on an exterior hood and avoid the operation inconvenience caused by the enclosure of an airflow capture booth. This new type of local exterior hood used the hood suction flow to stabilize the dynamic vortex shedding that was induced when a crossflow passed over a blockage plate, and therefore formed a hydrodynamics-stabilized local isolation area for efficient removing of the contaminant. The development process was performed in a test section of an open-circuit wind tunnel. The blockage plate and the exterior hood model were placed in a wind-tunnel test section so that the crossflow could be freely supplied by the airstream of the wind tunnel. The laser light sheet flow visualization method and the laser Doppler velocimeter were employed to reveal the characteristics of the flow field. Primary influential parameters were factored out of the measured velocity results so that a design procedure was proposed. Experiments using hot-wire type alcohol sensors to measure the toluene vapor concentration distributions showed that the capture efficiency of this type of actively controlled hood was remarkably higher than that of an uncontrolled hood.