Carbene Complexes of Groups VIA, VIIA and VIII

Dötz, Karl Heinz

doi:10.1007/978-1-4613-1785-2_4

Search citation statements

Order By: Relevance

Paper Sections

Select...

Results1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1997

2010

Publication Types

Select...

Article4

Other1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 5 publications

(2 citation statements)

References 307 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The methoxy group is a good leaving group and can easily be lost as methanol in a following step. This opens a general route for the preparation of heteroatom-substituted carbene complexes .…”

Section: Resultsmentioning

confidence: 93%

Synthesis of a Triosmium Carbonyl Cluster Complex with a Side-On-Coordinated Imine Ligand

et al. 1997

View full text Add to dashboard Cite

show abstract

Section: Resultsmentioning

confidence: 93%

Synthesis of a Triosmium Carbonyl Cluster Complex with a Side-On-Coordinated Imine Ligand

et al. 1997

View full text Add to dashboard Cite

show abstract

“…Heteroatom-stabilized carbene complexes play a central role in organometallic chemistry . They have found widespread application as reactive intermediates in organic synthesis, initiating a wide range of C−C and C−heteroatom bond-forming reactions . Moreover, heteroatom-stabilized carbenes, in particular N-heterocyclic ones, have been recognized as extraordinarily useful spectator ligands instead of or in addition to phosphine ligands .…”

mentioning

confidence: 99%

Novel Ruthenium-Mediated Conversion of Aldimines and Aminals to Aminocarbene Complexes

et al. 2002

View full text Add to dashboard Cite

The reaction of [RuCp(L)(CH3CN)2]PF6 (L = CH3CN, PMe3) with (E)-N-(phenylmethylene)-2-pyridinamine (py-NCHPh) affords the cyclic aminocarbene complexes [RuCp(L)(CPhNH-py)]PF6, whereas with L = PPh3, CO the reaction stops already at the stage of the imine complex [RuCp(L)(κ2 N,N-py-NCHPh)]PF6. This reaction arguably does not proceed via a direct 1,2-hydrogen shift but seems to involve hydrido iminoacyl intermediates as a result of C−H bond activation and deprotonation steps.

show abstract

Cyclopropanation Using an Iron‐Containing Methylene Transfer Reagent: 1,1‐Diphenylcyclopropane

2003

View full text Add to dashboard Cite

Cyclopropanation using an iron‐containing methylene transfer reagent: 1,1‐diphenylcyclopropane reactant: cyclopentadienyliron dicarbonyl dimer [C 5 H 5 (CO) 2 Fe] 2 , (0.50 mol equiv, 0.21 mol, 74.4 g; and ) intermediate: (η5‐C 5 H 5 )(CO) 2 FeCH 2 S+(CH 3 ) 2 BF 4 − product: 1,1‐diphenylcyclopropane solvent: nitromethane

show abstract

Carbene Complexes of Groups VIA, VIIA and VIII

Cited by 5 publications

References 307 publications

Synthesis of a Triosmium Carbonyl Cluster Complex with a Side-On-Coordinated Imine Ligand

Synthesis of a Triosmium Carbonyl Cluster Complex with a Side-On-Coordinated Imine Ligand

Novel Ruthenium-Mediated Conversion of Aldimines and Aminals to Aminocarbene Complexes

Cyclopropanation Using an Iron‐Containing Methylene Transfer Reagent: 1,1‐Diphenylcyclopropane

Contact Info

Product

Resources

About