1965
DOI: 10.1021/ja01094a018
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Carbethoxynitrene by α-Elimination. Reactions with Hydrocarbons1,2

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Cited by 169 publications
(63 citation statements)
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“…The results are recorded in Table 3. The main feature is the nearly identical ratio of insertion (16) to addition (15): 0.15 with 2a, 0.17 with 18 (8). This ratio is close to that observed in the electrochemical reduction of NFU in acetonitrile in the presence of cyclohexene: 16/15 = 0.1 I.…”
Section: ) Smithsupporting
confidence: 77%
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“…The results are recorded in Table 3. The main feature is the nearly identical ratio of insertion (16) to addition (15): 0.15 with 2a, 0.17 with 18 (8). This ratio is close to that observed in the electrochemical reduction of NFU in acetonitrile in the presence of cyclohexene: 16/15 = 0.1 I.…”
Section: ) Smithsupporting
confidence: 77%
“…[7]), and not the N-H bond of NFU (eq. [8]), is reduced. This is confirmed by the absence of hydrogen evolution during the preparative electrolysis of NFU on mercury [8] EtOCONHF + e + E~OCONF + f H2 20 and on platinum.…”
Section: Voltammettymentioning
confidence: 96%
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“…In the fields infancy, azides were decomposed thermally or photochemically to produce nitrenes; however, such strategies were unselective and low-yielding. [28] An improved protocol can be realised by rhodium-mediated decomposition of azides to form metallonitrenoids. Driver and coworkers used this approach to synthesize indoles 38 by a di-A C H T U N G T R E N N U N G rhodium(II)-catalyzed intramolecular CÀH amination from the decomposition of azidoacrylates 37 (Scheme 14).…”
Section: Nitrogen Heterocycles By C à H Aminationmentioning
confidence: 99%