This article briefly reviews the developments of the phosphors with high thermal stability and high efficiency for use in phosphor-converted LED (pcLED) packages by Lightscape Materials Inc. (wholly owned by The Dow Chemical Company). The current industry design objectives for pcLED packages are first outlined with emphasis on the emission spectral features required for target brightness and color characteristics for general illumination and back light unit for liquid crystal displays. There is a growing demand on thermal stability of the phosphor emission as the LED package power increases. A phenomenological analysis is described on luminescence loss and its relation to thermal stability of luminescence emission at elevated temperatures, which serves as an empirical guide in the search for new phosphor materials of high thermal stability. Finally, the formulations and luminescence properties of the proprietary carbidonitride and oxycarbidonitride phosphors are discussed.