Carbon–Carbon Bond Formation Reaction with Pd/rGO Composite

Kulkarni, Padmakar A.; Shendage, Suresh S.; Awale, Ashok Ganuji

doi:10.13005/ojc/340236

Cited by 5 publications

(1 citation statement)

References 28 publications

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“…Shendage and co-workers have introduced Pd NPs supported on reduced GO using aloe vera extract as reducing agent. [154] The obtained material was employed in the Suzuki reaction of aryl halides (I, Br, Cl) with arylboronic acids in EtOH/ H 2 O. Pd@GO demonstrated excellent yields for aryl iodides and bromides and low reactivity for chlorobenzene under conventional reaction conditions. The recyclability this catalyst investigated in the reaction of iodobenzene with phenylboronic acid being reused for seven times with yields in the range 110 to 89 %.…”

Section: Palladium-supported On Graphene or Graphene Oxidementioning

confidence: 99%

Carbon‐Derived Supports for Palladium Nanoparticles as Catalysts for Carbon‐Carbon Bonds Formation

Naghshbandi

Nájera

2019

ChemCatChem

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The review considers the variety allotropes of carbon to be used as supports for palladium and investigation of the resulting catalysts for carbon‐carbon forming reactions with focus on the catalyst recovery and effect of the solvent, base and catalyst loading in the efficiency of reactions. Specially, carbon nanotubes, C60 and graphene allowed the covalent functionalization with different ligands for palladium facilitating a lower leaching. Magnetic iron nanoparticles can be easily covered by charcoal, graphene oxide and carbon quantum dots facilitating the recovery of the supported catalyst. These heterogeneous catalysts are able to activate even aryl chlorides in cross‐coupling reactions such as Suzuki‐Miyaura, Mizoroki‐Heck and Sonogashira‐Hagihara in organic but also in aqueous media. All these features favoured the applicability of the materials for industrial processes.

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Section: Palladium-supported On Graphene or Graphene Oxidementioning

confidence: 99%

Carbon‐Derived Supports for Palladium Nanoparticles as Catalysts for Carbon‐Carbon Bonds Formation

Naghshbandi

Nájera

2019

ChemCatChem

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Benzophenone assisted UV-activated synthesis of unique Pd-nanodendrite embedded reduced graphene oxide nanocomposite: a catalyst for C–C coupling reaction and fuel cell

et al. 2019

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Carbon Nanocomposites: The Potential Heterogeneous Catalysts for Organic Transformations

Ambika

Pradeep

2021

COC

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: One of the major challenges in chemistry confronted by the chemists is the replacement of conventional homogeneous catalysts by heterogeneous catalysts for the development of green, sustainable and economical chemical processes. Recently, carbon based nanocomposites have attracted the attention of scientists due to their unique physical and chemical properties such as large surface area and pore volume, chemical inertness, high stability and high electrical conductivity. These NCs have been employed in energy storage, electronic devices, sensors, environmental remediation etc. Owing to the wide availability and low cost, carbon‐based‐materials have been utilized as supports for transition metals and other materials. The carbon based NCs offers a number of advantages such as high stability, easy recovery, reusability with often minimal leaching of metal ions, and green and sustainable approaches to heterogeneous catalysis for various organic transformations. Hence, they can be used as the substitute of the existing catalyst used for heterogeneous catalysis in industries. In this review, various processing methods for carbon based nanocomposites and their applications as heterogeneous catalyst for organic transformations like hydrogenation, oxidation, coupling, and multi‐component reactions, have been discussed.

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Carbon–Carbon Bond Formation Reaction with Pd/rGO Composite

Cited by 5 publications

References 28 publications

Carbon‐Derived Supports for Palladium Nanoparticles as Catalysts for Carbon‐Carbon Bonds Formation

Carbon‐Derived Supports for Palladium Nanoparticles as Catalysts for Carbon‐Carbon Bonds Formation

Benzophenone assisted UV-activated synthesis of unique Pd-nanodendrite embedded reduced graphene oxide nanocomposite: a catalyst for C–C coupling reaction and fuel cell

Carbon Nanocomposites: The Potential Heterogeneous Catalysts for Organic Transformations

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