Carbon-coated hierarchical spinel Fe1.5V1.5O4 nanorods: A promising anode material for enhanced lithium storage

Zhou, Yanli; Liu, Yanzhou; Wang, Qi; Sun, Xueqin; Liu, Ziquan; Liu, Ruicui; Jiang, Fuyi

doi:10.1016/j.jallcom.2018.02.093

Cited by 22 publications

(2 citation statements)

References 49 publications

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“…The P‐Fe 2 VO 4 /NCMNWs present higher discharge capacities of 1002, 533, and 364 mA h g −1 at 0.5, 5, and 10 A g −1 after 250, 500, and 1000 cycles, respectively. Based on the above comparison, the P‐Fe 2 VO 4 /NCMNWs exhibit superior high‐rate Li storage performance and long‐term stability, which present the best electrochemical performance compared to the previously reported iron vanadium oxide anode materials for LIBs to our knowledge (Table S2) . As the P‐Fe 2 VO 4 /NCMNWs present smaller specific surface area than Fe 2 VO 4 /NCMNWs, higher lithium ion storage capacity of P‐Fe 2 VO 4 /NCMNWs can be attributed to the existence of structure defects caused by the P doping, which could act as the storage sites during the electrochemical process…”

Section: Resultsmentioning

confidence: 57%

Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

et al. 2020

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The binary transition metal oxides have attracted great attention because of their considerable energy and power densities. However, they suffer from low reaction kinetics and large volume change, limiting their practical energy applications. The construction of a mesoporous structure with a large surface area, the development of a carbon matrix, as well as heteroatom doping can effectively overcome the above challenges. Herein, the synthesis of phosphorous‐containing Fe2VO4/nitrogen‐doped carbon mesoporous nanowires (P‐Fe2VO4/NCMNWs) is reported. In this unique structure, the atomic‐level P‐doping could increase the conductivity of Fe2VO4 by reducing its band gap, which is confirmed by DFT calculations. Furthermore, the phosphorus can covalently “bridge” the carbon layer and Fe2VO4 through P−C and Fe−O−P bondings. As a result, this anode material exhibits a high capacity (1002 mA h g−1 at 0.5 A g−1 after 250 cycles), excellent rate performance (448 mA h g−1 at 10 A g−1), and prominent long‐term cycling stability (533 mA h g−1 at 5 A g−1 after 500 cycles, 364 mA h g−1 at 10 A g−1 after 1000 cycles). All of these attractive features make the P‐Fe2VO4/NCMNWs a promising electrode material for high‐performance lithium‐ion batteries.

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Section: Resultsmentioning

confidence: 57%

Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

et al. 2020

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“…However, as one important kind of vanadates, iron vanadates with high abundance and environmental friendliness have been rarely studied as lithium/sodium‐ion anode materials . To our best knowledge, the first research on the iron vanadates as lithium‐ion battery anode can be traced back to Xia's work in 2009.…”

Section: Introductionmentioning

confidence: 99%

Fe₂VO₄ Hierarchical Porous Microparticles Prepared via a Facile Surface Solvation Treatment for High‐Performance Lithium and Sodium Storage

Luo

Huang

Liang

et al. 2019

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asymmetrical distribution of lithium resource. [3,4] On the other hand, sodiumion batteries (SIBs) have attracted great attention due to its abundant sodium resource, low cost, and the similar electrochemical reaction to LIBs, which is considered as the promising battery technology for large-scale energy storage applications. [5,6] But the commercial graphite does not work for SIBs as its interlayers are incapable to accommodate the sodium ions with larger ionic size. [7] As a result, one promising step to make the technological advancements is to develop the novel anode materials with both lithium and sodium storage ability.In this regard, transition metal oxides (M a O b , M = Mn, Fe, Co, Ni, Cu, etc.) based on the conversion reaction mechanism have been widely explored as the potential anode materials for LIBs and SIBs. Compared to graphite, transition metal oxides can provide higher theoretical specific capacity and higher safety, because the higher reaction potential can eliminate the lithium/sodium dendrite problem. [8][9][10][11][12][13][14][15] As an important member in the transition metal oxide family, transition metal vanadate has attracted much attention due to the multivalent properties of vanadium, which could deliver considerable capacity based on the multielectron transfer. [16,17] Additionally, the vanadium oxide presents strong VO bond during electrochemical process, suggesting the smaller volume change compared with traditional conversion-type electrodes. [18] For LIBs application, it is reported that the vanadium oxide can store lithium ions on the basis of the intercalation reaction mechanism, and provide the reaction sites for the conversion reaction between transition metal and metal oxide, preventing the aggregation of the obtained highly active metal nanograins, improving the cycling performance of the active material. [19,20] Furthermore, the binary metal oxide could exhibit higher electrochemical activity compared to the single metal oxide electrode. [21] Calcium vanadate nanowires have been synthesized as a novel sodium-ion anode material, which delivered a superior cycling performance (1600 cycles), excellent rate performance (5000 mA g −1 ), and an applicable reversible capacity (>300 mA h g −1 ). [16] Lou's group has developed triple-shelled Preventing the aggregation of nanosized electrode materials is a key point to fully utilize the advantage of the high capacity. In this work, a facile and lowcost surface solvation treatment is developed to synthesize Fe 2 VO 4 hierarchical porous microparticles, which efficiently prevents the aggregation of the Fe 2 VO 4 primary nanoparticles. The reaction between alcohol molecules and surface hydroxy groups is confirmed by density functional theory calculations and Fourier transform infrared spectroscopy. The electrochemical mechanism of Fe 2 VO 4 as lithium-ion battery anode is characterized by in situ X-ray diffraction for the first time. This electrode material is capable of delivering a high reversible discharge capacity of 799 mA h g −1 ...

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Importing Tin Nanoparticles into Biomass‐Derived Silicon Oxycarbides with High‐Rate Cycling Capability Based on Supercritical Fluid Technology

Shi

Huang

Xia

et al. 2019

Chemistry A European J

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Silicon oxycarbides (SiOC) are regarded as potential anode materials for lithium-ion batteries, although inferior cycling stability and rate performance greatlyl imit their practical applications. Herein, amorphous SiOC is synthesized from Chlorella by means of ab iotemplate methodb ased on supercritical fluid technology.O nt his basis, tin particles with sizes of several nanometersa re introduced into the SiOC matrix through the biosorptionf eature of Chlorella. As lithi-um-ionb attery anodes,S iOC and Sn@SiOC can deliver reversible capacities of 440 and 502 mAh g À1 after 300 cycles at 100 mA g À1 with great cyclings tability. Furthermore, as-synthesized Sn@SiOC presents an excellent high-rate cycling capability, which exhibits ar eversible capacity of 209 mAh g À1 after 800 cycles at 5000 mA g À1 ;t his is 1.6 times higher than that of SiOC. Such an ovel approach has significancef or the preparation of high-performance SiOC-based anodes.

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Carbon-coated hierarchical spinel Fe1.5V1.5O4 nanorods: A promising anode material for enhanced lithium storage

Cited by 22 publications

References 49 publications

Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Fe₂VO₄ Hierarchical Porous Microparticles Prepared via a Facile Surface Solvation Treatment for High‐Performance Lithium and Sodium Storage

Importing Tin Nanoparticles into Biomass‐Derived Silicon Oxycarbides with High‐Rate Cycling Capability Based on Supercritical Fluid Technology

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Carbon-coated hierarchical spinel Fe1.5V1.5O4 nanorods: A promising anode material for enhanced lithium storage

Cited by 22 publications

References 49 publications

Phosphorus‐Functionalized Fe2VO4/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Phosphorus‐Functionalized Fe2VO4/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Fe2VO4 Hierarchical Porous Microparticles Prepared via a Facile Surface Solvation Treatment for High‐Performance Lithium and Sodium Storage

Importing Tin Nanoparticles into Biomass‐Derived Silicon Oxycarbides with High‐Rate Cycling Capability Based on Supercritical Fluid Technology

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Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Phosphorus‐Functionalized Fe₂VO₄/Nitrogen‐Doped Carbon Mesoporous Nanowires with Exceptional Lithium Storage Performance

Fe₂VO₄ Hierarchical Porous Microparticles Prepared via a Facile Surface Solvation Treatment for High‐Performance Lithium and Sodium Storage