Carbon-coated Ni-Co alloy catalysts: preparation and performance for in-situ aqueous phase hydrodeoxygenation of methyl palmitate to hydrocarbons using methanol as the hydrogen donor

Shi, Yinteng; Ai, Li; Shi, Haonan; Gu, Xiaoyu; Han, Yujun; Chen, Jixiang

doi:10.1007/s11705-021-2079-1

Cited by 13 publications

(4 citation statements)

References 47 publications

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“…, hydrogenation pathway). A previous work has indicated that DCO 2 /DCO are dominating on the carbon-coated Ni–Co alloy, 26 and the hydrogenation pathway is minor. Here, the target product is C 15 .…”

Section: Resultsmentioning

confidence: 92%

“…Additionally, C 15 and C 16 can be converted to liquid C 6 -C 14 hydrocarbons via hydrogenolysis on Ni-Co alloy. 26 3.3.1. Effect of catalyst preparation condition.…”

Section: In Situ Aqueous Phase Hdo Performance Of Nico@mchsmentioning

confidence: 99%

“…Recently, hydrothermally stable carbon coated catalysts have been demonstrated to remarkably prevent the metal loss and sintering due to the confinement effect of carbon. 24 In previous works, 25,26 the carbon coated Ni–Sn IMCs and Ni–Co alloy (denoted as Ni–Sn@C and NiCo@C, respectively) have been prepared from the metal doped resorcinol–formaldehyde resin (RF). Compared with the metallic Ni, the Ni–Sn IMCs and Ni–Co alloy suppress graphitization, creating more pores in Ni–Sn@C and NiCo@C that show higher activity than Ni@C. However, the micropores are also dominating in the carbon shell, unfavorable for the mass transfer.…”

Section: Introductionmentioning

confidence: 99%

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In situ aqueous phase hydrodeoxygenation of methyl palmitate on Ni–Co alloy particles embedded in mesoporous carbon hollow sphere catalysts

Feng,

Zhou,

Wang

et al. 2024

New J. Chem.

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Section: Resultsmentioning

confidence: 92%

“…Additionally, C 15 and C 16 can be converted to liquid C 6 -C 14 hydrocarbons via hydrogenolysis on Ni-Co alloy. 26 3.3.1. Effect of catalyst preparation condition.…”

Section: In Situ Aqueous Phase Hdo Performance Of Nico@mchsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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In situ aqueous phase hydrodeoxygenation of methyl palmitate on Ni–Co alloy particles embedded in mesoporous carbon hollow sphere catalysts

Feng,

Zhou,

Wang

et al. 2024

New J. Chem.

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“…In a study by Shi et al [ 79 ] in 2022, HDO of methyl palmitate to hydrocarbons was carried out using methanol as a hydrogen donor. Resorcinol-formaldehyde resins were used as carbon source and Co and Ni were used as metal catalysts.…”

Section: Recent Applications Of Hdo For Clean Fuelmentioning

confidence: 99%

Green catalyst for clean fuel production via hydrodeoxygenation

YÜCEL,

DONAR,

ERGENEKON

et al. 2023

Turkish Journal of Chemistry

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The development of new fuel sources to replace nonrenewable fossil fuels has received substantial attention due to the ongoing demand for fossil fuels. Biomass and raw waste materials are crucial sources to produce suitable alternative fuels instead of nonrenewable fuels and offer a greener approach. Therefore, improving the fuel properties of biooils produced from the thermochemical conversion of biomass and raw waste materials is critical as it is used as an alternative to nonrenewable fuel. Developing an economical and eco-friendly method to produce sustainable and renewable oil by improving biooil containing large amounts of phenolic compounds has become imperative. One of the most intriguing and promising technologies for refining biooil to produce renewable fuels of comparable quality to conventional fossil fuels is the hydrodeoxygenation (HDO)-based process for converting biooil to renewable fuels. This method is almost one of the best improving methods described in the literature. At this point, it is of great importance that the HDO process is carried out catalytically. Carbon materials are preferred for both designing catalysts for HDO and supporting metal nanoparticles by providing chemically inert surfaces and tunable functional groups, high surface area and active sites. The HDO of biomass and raw waste materials has significantly advanced thanks to carbon-based catalysts. In this review, the effect of the surface character and catalytic ability of the carbon support, especially prepared by the green synthesis technique, on the HDO reaction during biooil improvement is discussed. Moreover, HDO reaction parameters and recent studies have been investigated in depth. Thus, green carbon catalysts’ role in clean fuel production via the HDO process has been clarified.

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Glucose-derived carbon-coated Ni–In intermetallic compounds for in situ aqueous phase selective hydrogenation of methyl palmitate to hexadecanol

Shi

Wang

et al. 2022

Reac Kinet Mech Cat

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Carbon-coated Ni-Co alloy catalysts: preparation and performance for in-situ aqueous phase hydrodeoxygenation of methyl palmitate to hydrocarbons using methanol as the hydrogen donor

Cited by 13 publications

References 47 publications

In situ aqueous phase hydrodeoxygenation of methyl palmitate on Ni–Co alloy particles embedded in mesoporous carbon hollow sphere catalysts

In situ aqueous phase hydrodeoxygenation of methyl palmitate on Ni–Co alloy particles embedded in mesoporous carbon hollow sphere catalysts

Green catalyst for clean fuel production via hydrodeoxygenation

Glucose-derived carbon-coated Ni–In intermetallic compounds for in situ aqueous phase selective hydrogenation of methyl palmitate to hexadecanol

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