Carbon Fiber-Reinforced Polyurethane Composites with Modified Carbon–Polymer Interface

Karaeva, Aida R.; Kazennov, Nikita V.; Мордкович, В. З.; Urvanov, Sergey A.; Zhukova, Ekaterina A.

doi:10.1007/978-3-319-62870-7_44

Cited by 5 publications

(4 citation statements)

References 6 publications

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“…15,16 Aligned CNTs, which are grown on carbon fiber (CF) surfaces via chemical vapor deposition method, can provide 3D reinforcement at the interlaminar regions. 15–20 Garcia et al. 15 showed a 69% improvement in interlaminar shear strength (ILSS), and Wicks et al.…”

Section: Introductionmentioning

confidence: 99%

A novel joining method by using carbon nanotube-based thermoplastic film for injection over-molding process

Matsumoto

Ishikawa

Tanaka

2019

Journal of Reinforced Plastics and Composites

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Hybrid thermoplastic composites are getting attention in light weight applications. The manufacturing process of hybrid composites is that discontinuous fiber-reinforced thermoplastics are injected onto the textile-reinforced thermoplastics through injection over-molding. The key topic of this process is to achieve a reliable interfacial bonding strength, which has a strong dependence on the molding conditions. As a novel approach, we adopted a carbon nanotube-based thermoplastic film to make nanoscale interconnections between different layers by inserting films between the layers. In this work, the following influences were investigated with respect to the interlaminar shear strength by short beam shear test: the (i) existence, (ii) dispersion state, (iii) concentration of carbon nanotubes, and (iv) injection over-molding conditions. Furthermore, the delaminated surface after short beam shear test was assessed via SEM observation. Consequently, polypropylene-injected hybrid composite with 1 wt% carbon nanotubes exhibited a 52% increase in interlaminar shear strength compared with the specimen without carbon nanotubes. Additionally, the combination of short carbon fibers, which were filled in injected polypropylene, and carbon nanotubes drastically enhanced the interlaminar shear strength. The optimization of carbon nanotube dispersion and molding condition provides strong improvement of interlaminar shear strength. However, excessive addition of carbon nanotube deteriorates the interlaminar shear strength.

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Section: Introductionmentioning

confidence: 99%

A novel joining method by using carbon nanotube-based thermoplastic film for injection over-molding process

Matsumoto

Ishikawa

Tanaka

2019

Journal of Reinforced Plastics and Composites

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“…10 To overcome this, various studies were conducted to improve mechanical, anti-flammable properties, adsorption characteristics and thermal properties by incorporation of fillers such as nanoparticles, particulates, fibers, agricultural wastes etc. [11][12][13][14] The large number of OH groups present on the cellulose surface helps in chemical modification using other species and allow derivatives to be formed. As the size of the cellulose is reduced to nanometer scale, it gains high surface area, which in turn provides a wide range of application in various fields.…”

Section: Introductionmentioning

confidence: 99%

Polyurethane and its composites derived from bio-sources: Synthesis, characterization and adsorption studies

Vijayan

Chandrashekar

et al. 2022

Polymers and Polymer Composites

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Polyols from chaulmoogra seed oil and grape seed oil were prepared by epoxidation and ring opening of oxirane ring using lactic acid in nitrogen atmosphere with a control over their functionality. Nanocellulose was derived from Desmostachya Bipinnata grass leaves and further surface functionalized. Modified nanocellulose was used as filler to prepare porous flexible bio-based polyurethane nanocomposites via in-situ polymerization. Adsorption of malachite green (MG) dye from wastewater using the prepared polyurethane composites was carried out. The effect of varying factors such as weight percentage of filers (modified nanocellulose), dosage of the adsorbent, pH, temperature and time on the MG adsorption have been studied experimentally. Material characterization for prepared materials was carried out using FTIR, NMR, TGA, DSC, and SEM along with other physical and chemical methods. FTIR results indicated the presence of peaks at 1704 cm−1 for –C=O stretching vibrations from urethane groups, 1531 cm−1 for –NH bending, 1232 cm−1 for –C–N stretching and 1105 cm−1 for –C–O stretching in the urethane group (–NHCOO–) thus, indicating the formation of urethane linkage in the polyurethane. Polyols with functionality around 2.8 were obtained from the oils, which has contributed to forming flexible polyurethanes. Morphological studies indicate the nano fibrillation of cellulose and closed-cell porosity in polyurethane and its composites. The flexible porous PU and its nanocellulose composites displayed improved thermal stability from 256.3°C to 270.5°C. Taguchi’s L27 orthogonal array have been applied for experimental design and optimization and the results were analyzed using ANOVA for raw and S/N ratio. It was found that pH is the most influential factor for adsorption lead by quantity of nanocellulose, time, dosage of the adsorbent and temperature.

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“…Developing nanotechnology allows the use of increasingly sophisticated nanocomposites [ 24 ]. The nanofillers used include nanofibers [ 25 , 26 ], graphene flakes [ 27 ], and carbon nanotubes [ 28 , 29 ]. When descending to the nanoscale, dispersion of the nanofiller becomes crucial.…”

Section: Introductionmentioning

confidence: 99%

Effect of MWCNTs on Wear Behavior of Epoxy Resin for Aircraft Applications

Mucha¹,

Krzyżak²,

Kosicka

et al. 2020

Materials

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The aim of the study is to assess the effect of multi-walled carbon nanotubes (MWCNTs) on the wear behavior of MWCNT-doped epoxy resin. In this study, a laminating resin system designed to meet the standards for motor planes was modified with MWCNTs at mass fractions from 0.0 wt.% to 2.0 wt.%. The properties of the carbon nanotubes were determined in Raman spectroscopy and HR-TEM. An examination of wear behavior was conducted on a linear abraser with a visual inspection on an optical microscope and SEM imaging, mass loss measurement, and evaluation of the wear volume on a profilometer. Moreover, the mechanical properties of MWCNTs/epoxy nanocomposite were evaluated through a tensile test and Shore D hardness test. The study shows that the best wear resistance is achieved for the mass percentage between 0.25 wt.% and 0.5 wt.%. For the same range, the tensile strength reaches the highest values and the hardness the lowest values. Together with surface imaging and a topography analysis, this allowed describing the wear behavior in the friction node and the importance of the properties of the epoxy nanocomposite.

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Carbon Fiber-Reinforced Polyurethane Composites with Modified Carbon–Polymer Interface

Cited by 5 publications

References 6 publications

A novel joining method by using carbon nanotube-based thermoplastic film for injection over-molding process

A novel joining method by using carbon nanotube-based thermoplastic film for injection over-molding process

Polyurethane and its composites derived from bio-sources: Synthesis, characterization and adsorption studies

Effect of MWCNTs on Wear Behavior of Epoxy Resin for Aircraft Applications

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