Crystalline silicon substrate visible light reflectivity is finely modified by a discrete growth of carbon nanofilm (CNF) on it by nanosecond pulsed laser deposition (PLD) technique. It is established that 71 nm thick CNF effectively reduces the high reflection of the substrate on average to 5% in the visible light wave range. The exact values of the thickness and refractive index of the carbon nanofilm are also determined via an analysis of reflection spectra.