Lithium-ion batteries (LIBs) are enabling the uptake
of electric
vehicles and providing grid-scale storage solutions for renewable
energy generation. However, it is vital to develop new and advanced
electrode materials for lithium-ion batteries to meet various applied
considerations such as cost, safety, toxicity, and performance. Here,
solid-state synthesized Y2W3O12 is
demonstrated as a high-rate active anode material in lithium-ion batteries,
producing an initial discharge capacity of 637 mAh/g although with
a very poor initial Coulombic efficiency of 35%. To improve the performance,
simple post-synthetic milling and carbon coating are investigated.
Carbon coating of the material leads to significant performance enhancement
in both the unmilled and milled samples. For instance, the unmilled
carbon coated electrodes maintained a high capacity of ∼140
mAh/g at 1600 mA/g after 2000 cycles with no capacity fading from
cycle 200 to 2000. Such a remarkable rate performance and an excellent
long-term cycling stability showcase the great potential of this unconventional
electrode material in fast-charge and high-power applications. This
facile post-synthesis process can be easily applied to other electrode
material candidates to enhance their electrochemical performance.